After she proves to be an excellent shot, Dean takes her as his (temporary) partner instead of Sam, who has become increasingly ill from the trials. The Yellow-Eyed demon, Azazel was resistant to salt and said to be impervious to the holy water. As Toni is a rival for heading the American operation, Arthur locks her in the bunker to die with the Winchesters. In a scene reminiscent of In "The Rupture," possessing a doctor at a hospital, Ardat kills a nurse and confronts a recovering Arthur over his failure to follow through on the job of assassinating Belphegor. He has no record of their activity in Portland, Oregon, where Sam and Dean are currently working, but Leviathans are there all the same. A month after his death, Kevin returns as a ghost, having been stuck in the veil between worlds due to Heaven being closed.
Along the way, Donna is forced to tell Doug the truth about monsters and her hunting lifestyle when they discover that the victims are being chopped up and sold as parts for monsters. After the world is saved, Dean reports Arthur's death to Sam along with the fact that it was probably a demon who did it, though they are unaware that it was Ardat. However, most angels have not actually met or spoken to God. Kevin, wanting to work in solitude to translate the half of the tablet that Castiel retrieved, later sends Linda elsewhere, explaining to Dean that he can't enjoy the world he is trying to save until it is saved. After the Winchesters open a rift to Apocalypse World, Arthur decides to join Dean on the mission, feeling that he is safer in another universe when Asmodeus will inevitably come looking for him. In "The Devil You Know", Bobby temporarily sells his soul to Crowley in order to locate Death.
In "Taxi Driver", Crowley finds Kevin, claiming that he captured Linda and tortured her for Kevin's location. Later on, Mick Davies retrieves Toni and informs her that he has sent for Ketch, who is shown preparing to leave the UK.
Some cases come about thanks to contact with people they knew before becoming hunters or contact with people they helped during previous hunts who turn to them for their expertise.
As Charlie is to be executed, Dean and Arthur attack the POW camp, killing several angels and liberating the prisoners. However, Mary quickly realizes that Arthur is lying and in fact killed Mick himself since he was shot in the head which a werewolf is unlikely to do. He then hires Arthur Ketch to help him search for Jack, made more urgent by the threat of an impending invasion by the Michael of an alternate reality. The next day, Mick joins the Winchesters in investigating Hayden's "mysterious" death, seeming conflicted by his actions.
After Hayden awakens and attacks him, clawing open Mick's shoulder, Mick uses the silver nitrate injection to kill her. It's later revealed that he wants Kevin in order to translate another Word of God tablet so he can learn how to open all the gates of Hell and release every demon in existence upon the world.
Later, Mick returns to his headquarters to find Arthur Ketch and Doctor Hess. Eileen eventually tracked down a demon working for the Prince of Hell Dagon and got Kelly's phone number from him before killing the demon with an angel blade. After believing he is about to die after having been turned into a vampire in "Live Free or Twi-Hard", Dean returns to say goodbye. In "Two Minutes to Midnight," Castiel reveals to Sam that Adam has now become Michael's vessel for the rapidly-approaching final battle which Sam admits is a possibility that they didn't really want to consider. Dean is impressed by Ben's cool headed behavior during the rescue, having put Ben in charge of helping the other children out a window. This event would haunt him for the rest of his life.
Her servant gives her a few weapons before she leaves. While Charlie is successful, she finds out the truth about Dick Roman and the Leviathans from his files and later teams up with the Winchesters to erase the drive. Overwhelmed, he later attacks the approaching hunters, forcing Sam to subdue him and lock Garth in the Impala's trunk. The life force Hydeker drained returned to his victims and they all recovered.
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